Harnessing potassium peroxymonosulfate activation of WO3/diatomite composites for efficient photocatalytic degradation of tetracycline

The increasing prevalence of pharmaceutical contaminants in aquatic ecosystems poses profound challenges for both environmental sustainability and public health. Addressing this pressing issue requires the development of innovative, cost-effective, and efficient remediation approaches. Here we report the synthesis of WO3/diatomite composites and their photocatalytic degradation in conjunction with potassium peroxymonosulfate (PMS) activation. By leveraging the synergistic effects, we observe a remarkable degradation of tetracycline, a significant pharmaceutical contaminant, under visible light. Analytically, we have elucidated the driving factors for the enhanced performance, emphasizing the optimal amount of WO3 (10%) in the composite and PMS concentration (3 mM). Specifically, the WO3/diatomite catalyst presents a degradation rate of 80.75% tetracycline (40 mg L−1) after 180 min of visible light irradiation. Also, we elucidate the primary roles of ˙SO4− radicals in driving the photocatalytic reaction using free radical trapping studies. Our approach not only offers a direct solution to controlling pharmaceutical contamination but also opens new possibilities for advancing the design of composite-based photocatalysts by taking advantage of nature-derived materials.


Introduction
While industrial progression has improved human living standards, it has concurrently posed environmental challenges. 1,2otably, the emerging healthcare sector discharges a considerable volume of pharmaceutical pollutants.4][5] Tetracycline possesses a highly stable chemical structure.When it is administered into the body through injection or oral delivery, only 20% is absorbed and metabolized, which in turn suggests that the remaining 80% is discharged.Human health may be at risk from antibiotic residues found at values ranging from 0.4 ng L −1 to 35.5 mg L −1 . 6ndoubtedly, addressing pharmaceutical pollution is imperative in maintaining our well-being.
][9][10] Extensive research underscores the notable effectiveness of advanced oxidation processes (AOPs), particularly photocatalysis, as a prime solution for tackling antibiotic pollution.The AOPs are not only an environmentally friendly process for effective treatment of antibiotics but also curtails the emergence of antibiotic-resistant bacteria in water systems, thereby addressing a major global health challenge. 11][14][15] The synthesis of WO 3 materials is well documented that offers a distinct advantage in terms of potential scalability and costeffectiveness for future manufacturing. 16,17Additionally, their non-toxic characteristics position them a potentially safe and sustainable option for water treatment applications, ensuring minimal environmental footprint while combating this urgent concern. 18,19Nonetheless, it is important to note that WO 3 photocatalysts also present unmet limitations.WO 3 has a relatively narrow band gap (E g ), which means it is prone to rapid charge recombination.The photocatalytic degradation of WO 3 may require extended reaction times compared to other photocatalysts, compromising the time efficiency of the photocatalytic degradation.Also, WO 3 materials can be susceptible to photocorrosion, especially under prolonged exposure to light, potentially diminishing their photocatalytic performance and overall stability. 20,21These fundamental limitations underscore the imperative for continued research aimed at optimizing WO 3 -based photocatalysis for efficient antibiotic removal from water sources.
To overcome these challenges and maximize its efficiency, the creation of appropriate composites is emerging as an innovative solution.3][24][25] Comprised of the fossilized remains of diatoms, tiny aquatic plants, its unique physicochemical properties provide a solid foundation for various environmental applications, including water purication. 227][28] Furthermore, diatomite demonstrates versatility as a catalyst support and a reservoir for essential diatomic species, such as molecular oxygen (O 2 ) or hydrogen peroxide (H 2 O 2 ), pivotal co-reactants in photocatalytic reactions. 22oncurrently, the use of potassium peroxymonosulfate (2KHSO 5 $KHSO 4 $K 2 SO 4 , PMS) activation emerges as a strategic approach to enhance the reaction kinetics of photocatalysts. 29otably, PMS introduces highly reactive sulfate radicals (cSO 4 − ), 1][32] This process additionally offers the potential to ameliorate the issue of photocorrosion, with PMS actively promoting sulfate radical formation, thereby reducing catalyst degradation risks and enhancing stability. 20,33The rational combination of diatomite and PMS activation leverages these collective advantages, fostering a synergistic platform poised to amplify the catalytic activity of WO 3 , thus offering a promising pathway for more efficient antibiotic degradation within water treatment processes.Despite a remarkable advancement in developing WO 3 -based photocatalytic materials for degrading tetracycline, the complicated and high-cost synthesis of these materials remains an unmet hurdle.Also, these catalysts oen present a broad band gap value, hindering their activity exclusively under UV radiation, which consequently limits the applicability of in living conditions.
Here we present the fabrication of a composite photocatalyst by anchoring WO 3 onto diatomite using a straightforward mechanical mixing method.The resultant WO 3 -loaded diatomite materials demonstrate remarkable efficiency in removing tetracycline under visible light exposure in assistance of PMS.Our ndings emphasize that the exceptional performance of WO 3 /diatomite composites, when activated with PMS, can be attributed to the synergistic interactions between these components.This innovative integration effectively addresses the inherent limitations of WO 3 , ultimately advancing its potential as a robust solution for combating antibiotic pollution, with promising implications for further scientic investigation and application.This study also lays the foundation for advancing the design of innovative photocatalysts with heightened performance and multifaceted capabilities.

Fabrication of materials
WO 3 nanoplates were synthesized through a hydrothermal approach.An initial solution was prepared by dissolving 4.125 g of Na 2 WO 4 $2H 2 O (Sigma-Aldrich, $99%) and 2.125 g of NaNO 3 (Sigma-Aldrich, $99%) in 100.0 mL of distilled water.Subsequently, 60.0 mL of aqueous HNO 3 (Xilong, China, 68% wt) was slowly added to the above solution, magnetically stirred for one day at room temperature.The resulting solution was then transferred to a 200 mL Teon autoclave and subjected to a hydrothermal condition at 150 °C for one day, aer which it was cooled naturally to room temperature.The resulting yellow precipitate was collected, thoroughly washed with distilled water, and subsequently dried at 80 °C for 120 minutes.Finally, the obtained powder was annealed in an air atmosphere at 400 °C for 120 minutes to produce WO 3 nanoplates.The diatomite material was sourced from Phu Yen province, Vietnam, and underwent milling to produce a powder characterized by small and relatively uniform particle sizes.
The preparation of WO 3 /diatomite composites involved an ultrasonic process, varying the WO 3 mass percentage at 3%, 5%, 10%, 30%, and 50% by weight.Initially, WO 3 powder was introduced into a beaker containing a diatomite suspension in 20.0 mL of deionized (DI) water.The amalgamation was subsequently subjected to one hour of sonication followed by one hour of stirring.The resulting mixture was then dried for 240 minutes at 80 °C.Finally, the obtained powder was further processed by grinding using mortars and pestles.The overall process of the synthesis is schematically illustrated in Scheme 1.

Characterization techniques
Various analytical techniques were applied for a comprehensive characterization.To investigate the crystal structure, X-ray diffraction (XRD) patterns were analyzed using a Siemens/ Bruker D5000 X-ray powder diffractometer system, employing Cu-Ka radiation (l = 1.54064Å).Chemical bonds in the materials were examined by capturing their characteristic molecular vibration using an FT-IR spectrophotometer (Jasco FT-IR-4700).The morphology of the samples was visualized through scanning electron microscopy (SEM) images (JMS-IT500).The elemental composition of the materials was assessed using energy-dispersive X-ray spectroscopy in conjunction with scanning electron microscopy (SEM-EDX, JEM 2100, JEOL).Optical properties were studied using UV-Vis diffuse reection spectroscopy (DRS) on a Jasco V-770 UV/Vis spectrophotometer.Details about the material's conduction band were studied through an electrochemical approach using the Mott-Schottky (MS) plot on three-electrodes Biologic SP200.Solution concentrations were analyzed using a UV-Vis spectrophotometer (Hitachi U-2910).

Experimental details of the photocatalytic degradation
This investigation aimed to evaluate the potential of WO 3 / diatomite composites to activate PMS (Acros Organics, 4.5% active oxygen) for the degradation of tetracycline under visible light.To determine the optimal material composition for achieving the highest photocatalytic efficiency, a systematic assessment of the photocatalytic performance was conducted, varying the WO 3 concentrations in the WO 3 /diatomite composite.The reactions were carried out in a 100 mL glass beaker (7.2 cm in height and 5 cm in diameter, the distance from the lamp height to the solution is 12 cm) containing 60 mL tetracycline solution, which was dissolved from tetracycline hydrochloride 500 mg, with continuous magnetic stirring.Initially, to establish adsorption/desorption equilibrium, 12 mg of photocatalyst was introduced into the target tetracycline solution and stirred for 150 minutes in the absence of light.Subsequently, the suspension was illuminated for 180 minutes using a sunshine simulator lamp (Osram Ultra-Vitalux 300 W, 230 V) equipped with a UV cut-off lter (l > 420 nm) and a cooling fan.To analyze the absorption prole, samples were centrifuged, placed in cuvettes, and subjected to UV-Vis monitoring at 30 minutes intervals for a total of 180 minutes.The effectiveness of the photocatalytic tetracycline degradation of the materials is quantied through eqn (1). 34%Þ where h is photocatalytic degradation efficiency, C 0 is the absorption intensity of the tetracycline solution aer the adsorption/desorption reaches equilibrium, C t is the absorption intensity of the solution at time t.The rst order kinetic equation (eqn (2)) is used to get the reaction rate constant of the tetracycline decomposition.
where k is the reaction rate constant of the ideal rst-order equation (min −1 ).The plot of ln C 0 C versus t gives a linear behavior, and k is calculated from its slope.
To empirically identify the dominant factor driving the photocatalytic activity, we conducted reactive species trapping tests. 35In these experiments, we introduced 1 wt% of specic scavengers -IPA, TBA, K 2 Cr 2 O 7 , KI, and BQ-to the photocatalyst, targeting cOH and cSO 4 − , cOH, e − , h + , and cO 2 − , respectively.
The presence of scavengers was aimed at reducing the efficiency of photocatalytic performance, thereby elucidating the roles played by each type of free radicals during the photocatalytic activity.

Structural characterizations
The crystal structures of the diatomite, WO 3 , and WO 3 /diatomite composites with varying WO 3 concentrations can be informed by their distinct X-ray diffraction peaks (Fig. 1).The characteristic diffraction peaks of WO and Fe 2 O 3 constitute the majority of its composition. 28The 3%, 5%, and 10% WO 3 /diatomite samples exhibit peaks indicative of diatomite, conrming the dominant presence of diatomite within these composite materials.Interestingly, in the 30% and 50% WO 3 /diatomite composites, we also observe characteristic peaks of WO 3 , specically corresponding to the lattice faces (002), ( 020), ( 200), (022), and (202).These XRD results provide critical insights into the structural composition of the composites, highlighting the coexistence of WO 3 and diatomite.Furthermore, the specic chemical bonding vibrations of WO 3 , and WO 3 /diatomite composites were analyzed through FT-IR spectra (Fig. 2).In the FT-IR spectra of WO 3 , the discernible peaks spanning the range of 700 cm −1 to 900 cm −1 are attributed to the stretching vibrations of W]O and W-O-W bonds. 36otably, these characteristic peaks of WO 3 become more pronounced as the WO 3 content in the composites increases, consistent with the trends observed in the XRD patterns.The pronounced peak at 1098 cm −1 is attributed to the stretching mode of siloxane (Si-O-Si) bonds, underlining the presence of these bonds in the materials. 37Additionally, the peak at 471 cm −1 corresponds to the asymmetric stretching mode of siloxane bonds. 38Furthermore, the vibration of O-H bonds contributes to the peak observed at 796 cm −1 .It is worth noting that the broad absorption peak at 3442 cm −1 is associated with the stretching mode of the -OH group, stemming from water molecules absorbed on the material's surface.This adsorption can be attributed to the porous structure inherent in diatomite, which facilitates water adsorption.This comprehensive FT-IR analysis not only validates the materials' elemental composition in supporting the XRD results about the successful combination of WO 3 and diatomite but also sheds light on their chemical characteristics and surface properties, further enriching our understanding of their potential applications in photocatalysis.

Morphological
Scanning electron microscopy (SEM) images are captured to visualize the materials' morphology.Fig. 3a and b vividly depicts the irregular arrangement of structural elements comprising WO 3 nanoplates.The acid treatment's effect on diatomite's morphology is evident in Fig. 3c and d, revealing a noticeable enhancement in pore visibility and a substantial reduction in contaminants when compared to untreated diatomite.This treatment renders the diatomite highly conducive for the incorporation of WO 3 , given the increased availability of sites within the porous structure.Fig. 3e and f provides compelling evidence of the successful creation of WO 3 /diatomite composite materials.Here, WO 3 nanoplates are adeptly integrated into the porous framework of diatomite, lling the voids and interstices effectively.The specic surface areas (S BET ) of raw diatomite, acid-treated diatomite and 10% WO 3 /diatomite were 21.35, 24.92 and 31.34m 2 g −1 , respectively.The S BET of the 10% WO 3 /diatomite sample exhibits a more signicant increase compared to the acid-treated diatomite, which can be attributed to the presence of smaller-sized WO 3 particles on the diatomite carrier.The presence of such a porous structure within diatomite is a signicant advantage, as it offers a straightforward means of incorporating additional porosity into the material a characteristic of paramount importance in the context of investigations aimed at antibiotic degradation.These observations collectively underscore the potential of this material as a promising candidate for further exploration in the realm of antibiotic degradation studies, benetting from its intricate porous architecture and the ease with which it can be tailored to specic applications.
The elemental composition of the 10% WO 3 /diatomite sample is discernible through analysis of the energy-dispersive X-ray spectroscopy (EDX) spectra.As illustrated in Fig. 4, the obvious presence of WO 3 and its characteristic peaks are conspicuously evident in the 10% composite sample.Once more, the EDX spectrum unequivocally conrms the successful integration of WO 3 into the diatomite matrix, reaffirming the presence of WO 3 within the diatomite structure.These ndings provide crucial insights into the material's elemental composition, further substantiating its suitability for the intended applications and conrming the effective synthesis of the composite material.

Optical properties
We have explored the optical properties of WO 3 and their composite materials using diffuse reectance spectroscopy (DRS).The DRS spectra of the composite samples with varying WO 3 concentrations are presented in Fig. 5a.To approximately quantify the band gap energy of these materials, we employ the well-established Tauc plot function (eqn (3)). 39,40 where a, h, n, A, and E g represents the absorption coefficient, Planck's constant, the light frequency, a constant, and the band gap energy of the material, respectively; r = 2 for indirect transitions.
The obtained band gap (E g ) of WO 3 is 2.80 eV and the band gap of the composite samples increases from 2.81 to 2.94 eV (Fig. 5b).The increase of the band gap of the composite sample is explained by the existence of SiO 2 and some the others compounds in the diatomite mineral.The DRS results and band gap values of the 30% WO 3 /diatomite and 50% WO 3 /diatomite composite materials do not exhibit any signicant differences, which suggests that the WO 3 content reaches 30 wt% in the composite, the optical properties of the composites have gradually stabilized.Although there is a slight increase of the band gap energies in the composite samples, the composite samples still maintain the ability to interact with light in the visible region.
To ascertain the electrical characteristics of the materials, we conducted Mott-Schottky plots for both WO 3 and the 10% WO 3 /  diatomite composite samples (Fig. 6).The Mott-Schottky relationship entails the measurement of apparent capacitance as a function of potential under depletion conditions, governed by eqn (4). 41 where C is the capacitance of the space charge region, 3 is the dielectric constant of the semiconductor, 3 0 is the permittivity of free space, N is the donor density, A is the area of the interface or the electrode, V a is the applied potential, V  is the at band potential, k is the Boltzmann constant, and T is the temperature.
Based on our Mott-Schottky analysis (Fig. 6a), we obtained at band potentials of −0.62 V vs. NHE for WO 3 and −0.58 V vs. NHE for 10% WO 3 /diatomite composite.These values are indicative of the materials' electrical behavior and their potential as semiconductor materials.It is noteworthy that both samples display Mott-Schottky plots with a positive slope, unequivocally establishing their classication as n-type semiconductors.The V  values of both WO 3 and 10%WO 3 /diatomite are almost equal.This can be attributed to the fact that WO 3 serves as the primary semiconductor material, while diatomite functions merely as a carrier.Additionally, there is no chemical bonding between WO 3 and diatomite, which means that the electrical properties of WO 3 remain unaffected.To conrm the band gap value of WO 3 , a photoluminescence spectrum of WO 3 nanoparticles was conducted at room temperature using an excitation wavelength of 300 nm (Fig. 6b).The analysis revealed that the WO 3 exhibited a maximum emission wavelength of 440-442 nm (∼2.80-2.82eV), which is consistent with the ndings from the DRS and Tauc band gap (Fig. 5).

Photocatalytic tetracycline degradation
To assess the efficacy of photocatalytic antibiotic degradation over the as-prepared materials, we use a tetracycline solution with an initial concentration of 40 mg L −1 as the target pollutant for degradation using 200 mg L −1 of the catalyst.Prior to activating PMS, a series of preliminary tests are conducted to evaluate the antibiotic degradation capacity of WO 3 , diatomite, and WO 3 /diatomite composites with varying WO 3 concentration, changing of pH value during in the photocatalytic process (Fig. 7c).This systematic approach enables our understanding about the capability of the materials in removing tetracycline, informing the most effective composition for more in-depth studies.
To reach adsorption/desorption equilibrium, the solution is agitated in the absence of light for 150 minutes.Control samples without a photocatalyst (blank) are analyzed and compared under identical conditions, providing experimental baseline for our assessments.Under light irradiation for 180 minutes, a minor fraction (2%) of the tetracycline solution spontaneously decomposed in the absence of a catalyst.Due to its porous structure, diatomite exhibited superior tetracycline adsorption capabilities compared to the WO 3 sample.However, the photocatalytic degradation efficiencies for bare WO 3 and diatomite samples remained relatively low, at 2.34% and 3.41%, respectively.Among the composite samples, 10% WO 3 /diatomite composite achieves the highest degradation efficiency (10.93%) aer 180 minutes of irradiation.This underscores the pivotal role of WO 3 as a key factor for the degradation of antibiotics.Notably, the efficiency diminished as WO 3 concentration increased to 30% (6.78%) and 50% (6.25%) within the composite material.This decline can be attributed to the excessive presence of WO 3 , which lls the pores in the diatomite, limiting the activation of WO 3 only on its surface.Furthermore, when diatomite is excessively coated with WO 3 , its function as a carrier diminishes.The degradation kinetics of tetracycline solutions during the tetracycline degradation follow rst-order kinetics, as described by eqn (2).As detailed in Table 1, the rate constant for the 10% WO 3 /diatomite photocatalyst aer 90 minutes of exposure is calculated to be 0.00398 min −1 , signifying the sample's superior efficacy in the degradation of antibiotics.These ndings underscore the potential of the 10% WO 3 /diatomite composite as an efficient photocatalyst for the degradation of tetracycline.Consequently, the 10% WO 3 /diatomite sample is selected as the optimal catalyst for subsequent experiments.3.4.1.Photocatalytic PMS activation activity.In our investigation of antibiotic degradation using the 10% WO 3 /diatomite composite sample through PMS activation, we use the same conditions as in the previous experiment (a tetracycline solution with a concentration of 40 mg L −1 and a catalyst concentration of 200 mg L −1 ).The degradation efficiency as a function of varying PMS concentrations, ranging from 1 mM to 4 mM, is presented in Fig. 7b.Our results suggest that PMS can makes the solution more acidic due to its ability to dissociate H + ion (Fig. 7c) and 3 mM is the optimal PMS concentration for generating the highest amount of cSO 4 − radicals conducive for photocatalytic tetracycline degradation.Specically, a remarkable degradation efficiency of nearly 81% is observed at this PMS concentration.Beyond this PMS concentration (e.g., 4 mM), there is a decline in degradation efficiency, dropping to 67.86%.The observed change in efficiency at elevated concentrations could be due to the overproduction of cSO 4 − and cOH radicals.These excessive radicals, at higher concentrations, could adversely affect degradation efficiency.Explicitly, they might react with HSO 5 − to form cSO 5 − radicals as described in eqn ( 5) or engage with one another to yield S 2 O 8 2− anions as described in eqn (6).In addition, Table 2 shows that the kinetic constant k of the 10% WO 3 /diatomite composite, in which the k value for the 3 mM PMS is 0.0416 min −1 .This result is pertinent to the efficiency degradation of 3 mM PMS in the 10% WO 3 / diatomite composite.The observations elucidate the complexities inherent in the PMS activation process.They emphasize the necessity to nely tune the PMS concentration to attain peak photocatalytic degradation efficiency.It is also evident that steering clear of specic concentrations can avert undesirable side reactions that might impede the degradation process.TOC analysis results (Fig. 7d) also show that in the presence of PMS, the tetracycline mineralization of the 10% WO 3 /diatomite samples is better, meaning that CO 2 produced in this process is more intense.This result is completely consistent with the mechanism of generating more free radicals with stronger oxidizing properties in this reaction.Moreover, Table 3 shows the strong photocatalytic activity for tetracycline degradation of the 10% WO 3 /diatomite system compared to other recently published materials.3.4.2.Photocatalytic degradation mechanism.To gain a comprehensive understanding of the primary constituents driving the photocatalytic reaction, we conduct a series of free radical trapping studies.These experiments are meticulously designed, wherein we incorporate quenching agents like isopropyl alcohol (IPA), potassium dichcromate (K 2 Cr 2 O 7 ), potassium iodide (KI), p-benzoquinone (BQ), and tert butyl alcohol (TBA) into the 10% WO 3 /diatomite composite sample.Each of these agents was added at a consistent weight percent of 1%, serving the purpose of selectively suppressing different reactive species.The introduction of various quenching agents like K 2 Cr 2 O 7 , KI, TBA, and BQ, which results in degradation efficiencies of 67.85%, 67.78%, 67.85%, and 60.78% respectively, demonstrated only a marginal effect on the photocatalytic degradation efficiency of tetracycline (Fig. 7e).Such observations indicate that while the targeted species by these agents, i.e., e − , h + , cOH, and cO 2 − , do participate in the photocatalytic activity, they are not the primary contributors to the degradation mechanism.In contrast, the introduction of IPA causes a substantial reduction, bringing the degradation efficiency down to 59.10% (see Table 4).Given IPA's capacity to scavenge both cOH and cSO 4 − radicals and considering that cOH plays a relatively minor role in the photocatalytic degradation, it becomes evident that the cSO 4 − radical holds paramount importance in driving the photocatalytic processes.
Understanding the sustainable efficacy and longevity of photocatalytic materials is pivotal for their practical applications.With this motivation, we delved into the cyclical degradation performance of the 10% WO 3 /diatomite composite sample in the presence of 3 mM PMS, as illustrated in Fig. 7f.Impressively, the sample's efficiency in degrading tetracycline remained relatively stable for the initial three cycles.Even aer ve cycles, despite a minor dip in performance, the sample sustained an efficiency of up to 71%.It is noteworthy that during the rst 30 minutes of radiation across all ve cycles, there was a pronounced decrease, likely attributable to the presence of PMS.This consistent performance, even aer multiple cycles, accentuates the sample's remarkable resilience and underscores its potential in tetracycline reduction.
Drawing from the comprehensive analysis of our experimental data, we have delineated a potential mechanism, graphically illustrated in Fig. 8. Upon a composite of WO 3 and diatomite is formed, the newly established WO 3 /diatomite interface gives rise to a reduction in the optical band gap of the composite compared to the bare states.Such an interface also modulates the electron density in the composite and mitigates electron-hole recombination process.Notably, central to this mechanism is the prominent role of the cSO 4 − radicals, which emerges as the principal agent driving the degradation of tetracycline in the 10% WO 3 /diatomite composite sample.It is evident from our ndings that the activation of PMS can be achieved either via e − or cO 2 − , leading to the formation of cSO 4 − radicals (eqn ( 7)-( 13)).This formation enhances the separation efficacy of electron-hole pairs.It is also worth noting that h + possesses the ability to interact with PMS, resulting in the production of cSO 5 − , a radical with comparatively diminished reactivity than its counterpart, cSO 4 − (eqn ( 14) and ( 15)).
Intriguingly, at elevated concentrations of cSO 5

−
, it has the potential to transform into cSO 4 − (eqn ( 16)).Uniquely, as a-Fe 2 O 3 is one of the two primary components of diatomite, it is possible to take them into account as iron ions are highly reactive to HSO 5 − to generate SO 4 2− and OHc (eqn ( 17)-( 19)).
Overall, the results from the free radical trapping test suggest that e − and h + have the capability to produce cO 2 − and cOH radicals, respectively.However, their roles seem to be supplementary, acting as secondary agents in the comprehensive efficiency of tetracycline decomposition (eqn ( 20)).This

Conclusion
In this study, we have proposed the rst development of WO 3 / diatomite composite photocatalysts, marking a signicant advancement in the effective removal of antibiotics.This achievement is accentuated when paired with PMS activation under visible light.The enhanced photocatalytic performance in antibiotic degradation can be attributed to the meticulous formation of the composite and the judicious selection of an optimal PMS concentration.Specically, the 10% WO 3 /diatomite composites, when combined with the ideal PMS concentration, emerge as a robust and enduring photocatalyst.In addition, the WO 3 /diatomite catalyst can degrade 80.75% tetracycline (40 mg L −1 ) aer 180 min-visible light irradiations.Furthermore, WO 3 /diatomite/PMS systems are stable (achieved up to 71% of tetracycline degradation performance aer ve cycles).Delving deep into these mechanisms not only enriches our understanding but also opens avenues for impactful applications in the realm of antibiotic degradation.

Fig. 5
Fig. 5 DRS spectra of the as-prepared materials (a) and estimated band gap of WO 3 and 10% WO 3 /diatomite composite (b).

Fig. 7
Fig. 7 Photocatalytic activity of the materials: (a) photocatalytic tetracycline degradation of the materials under visible light irradiation.(b) Photocatalytic tetracycline degradation of the materials under visible light irradiation with PMS activation.(c) Change of pH value.(d) Tetracycline mineralization.(e) Free radical trapping studies of the 10% WO 3 /diatomite composite, and (f) stability of the 10% WO 3 /diatomite composite for five repeated photocatalytic runs.

Table 3
A comparison of photocatalytic activity related to WO 3 immobilized on diatomite substrate and photocatalyst degradation tetracycline

Table 4
The photocatalytic degradation efficiency of tetracycline in trapping test